全文获取类型
收费全文 | 10601篇 |
免费 | 218篇 |
国内免费 | 53篇 |
专业分类
化学 | 6875篇 |
晶体学 | 78篇 |
力学 | 335篇 |
数学 | 1830篇 |
物理学 | 1754篇 |
出版年
2021年 | 119篇 |
2020年 | 113篇 |
2019年 | 98篇 |
2018年 | 83篇 |
2017年 | 78篇 |
2016年 | 163篇 |
2015年 | 157篇 |
2014年 | 183篇 |
2013年 | 601篇 |
2012年 | 463篇 |
2011年 | 567篇 |
2010年 | 317篇 |
2009年 | 261篇 |
2008年 | 548篇 |
2007年 | 521篇 |
2006年 | 512篇 |
2005年 | 506篇 |
2004年 | 406篇 |
2003年 | 387篇 |
2002年 | 396篇 |
2001年 | 171篇 |
2000年 | 166篇 |
1999年 | 112篇 |
1998年 | 109篇 |
1997年 | 125篇 |
1996年 | 146篇 |
1995年 | 99篇 |
1994年 | 123篇 |
1993年 | 126篇 |
1992年 | 122篇 |
1991年 | 119篇 |
1990年 | 114篇 |
1989年 | 89篇 |
1988年 | 104篇 |
1987年 | 106篇 |
1986年 | 80篇 |
1985年 | 162篇 |
1984年 | 162篇 |
1983年 | 136篇 |
1982年 | 150篇 |
1981年 | 165篇 |
1980年 | 165篇 |
1979年 | 145篇 |
1978年 | 153篇 |
1977年 | 150篇 |
1976年 | 134篇 |
1975年 | 129篇 |
1974年 | 121篇 |
1973年 | 128篇 |
1972年 | 82篇 |
排序方式: 共有10000条查询结果,搜索用时 791 毫秒
991.
Soo-Jin Park George G. Chase Kwang-Un Jeong Hak Yong Kim 《Journal of Sol-Gel Science and Technology》2010,54(2):188-194
Flexible mats of titania fibers are prepared by calcination of electrospun polyvinylpyrrolidone fibers containing titanium
isopropoxide precursor. Structural investigation of the calcinated nanofibers by X-ray diffraction (XRD) and electron diffraction
(ED) combined with the morphologies by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) show
the titania fibers, with an average diameter of 180 nm, were comprised of anatase and rutile crystals. The mechanical, chemical
and thermal properties of the titania fiber mats are further investigated by the techniques of Instron mechanical tester,
thermogravimetric analyzer (TGA), and Fourier transform infrared spectroscopy (FT-IR). The titania fiber mat prepared in this
method exhibited a significant flexibility with 461 MPa Young’s modulus. 相似文献
992.
993.
George Ellis 《Foundations of Physics》2018,48(10):1226-1245
The present day standard cosmological model is a great theoretical achievement. This chapter surveys the main themes that have arisen and issues that are still oustanding. 相似文献
994.
Minas P. Georgiadis Violetta Constantinou-Kokotou George Kokotos 《Journal of carbohydrate chemistry》2013,32(5):739-748
ABSTRACT 6′-N derivatives of neamine with alanine, phenylalanine and lysine were synthesized either using an active esters method in one step under controlled conditions, or using a mixed anhydride method after blocking every functional group of neamine and leaving the 6′-amino group free to react. Similarly N,N′-diamino acid and monoamino acid derivatives of 2-deoxystreptamine were synthesized. 相似文献
995.
996.
997.
998.
999.
George C. Rhoderick 《Analytical and bioanalytical chemistry》2010,398(3):1417-1425
Studies of climate change increasingly recognize the diverse influences exerted by terpenes in the atmosphere, including roles
in particulates, ozone formation, and their oxidizing potential. Measurements of key terpenes suggest atmospheric concentrations
ranging from low pmol/mol (parts per trillion) to nmol/mol (parts per billion), depending on location and compound. To accurately
establish concentration trends, assess the role of terpenes in atmospheric chemistry, and relate measurement records from
many laboratories and researchers, it is essential to have good calibration standards. The feasibility of preparing well-characterized,
stable gas cylinder standards for terpenes at the nmol/mol level is not yet well established. Several of the world’s National
Metrology Institutes (NMIs) are researching the feasibility of developing primary and secondary reference gas standards at
the nmol/mol level for terpenes. The US NMI, the National Institute of Standards and Technology, has prepared several nmol/mol
mixtures, in treated aluminum gas cylinders, containing terpenes in dry nitrogen at nominal 5 nmol/mol for stability studies.
Overall, 11 terpenes were studied for stability. An initial gas mixture containing nine terpenes, one oxygenate, and six aromatic
compounds, including benzene as an internal standard, was prepared. Results for four of the nine terpenes in this initial
mixture indicate stability in these treated aluminum gas cylinders for over 6 months and project long term (years) stability.
Interesting results were seen for β-pinene, which when using a linear equation rate decline predicts that it will reach a
zero concentration level at day 416. At the same time, increases in α-pinene, d-limonene (R-(+)-limonene), and p-cymene were observed, including camphene, a terpene not prepared in the gas mixture, indicating a chemical transformation
of β-pinene to these species. Additional mixtures containing combination of either α-pinene, camphor, α-terpinene, and benzene
indicate a second-order quadratic rate decline for the α-pinene and α-terpinene, a linear rate decline for camphor, and a
second-order quadratic rate increase of camphene. 相似文献
1000.